About shock
Cal-hypo adds calcium: about 0.7 ppm of calcium hardness for every 1 ppm of chlorine. One shock at CYA 40 adds about 10 ppm, which matters in vinyl pools and where the fill water is already hard. If you shock often, 0.7 gal of 10% liquid chlorine does the same job with no calcium.
Dissolve cal-hypo in a bucket of pool water first and pour it in front of a return. Never mix it with any other chlorine product, especially trichlor tablets: the combination can ignite.
A shock (SLAM) is not one dose. Hold free chlorine at the shock level, testing and topping up several times a day, until combined chlorine is 0.5 ppm or less, the overnight loss is 1 ppm or less, and the water is clear.
Dosing a 5,000 gallon pool
That is about the size of a 15 ft round × 52 in above-ground pool (about 5,070 gal), or a 16 ft round × 48 in above-ground pool (about 5,260 gal). At 5,000 gallons, most doses are measured in fluid ounces or ounces rather than gallons or pounds. Above-ground pools of this size usually have vinyl liners, so keep calcium hardness modest and add everything in front of a return jet, away from the liner wall.